What *is* harmful is collecting established colonies. Worse? An establish colony hardly ever thrives after being collected, the trauma is just too much. The workers never adjust. It's not worth it.
So, if you want to keep ants learn when your local species fly and catch those queens. Don't feel bad about catching two or three for each colony you intend to raise. (Queens often randomly die early on.)
Put them in test tubes and there begins a multi-year commitment to an incredible pet.