@lain i still like Philosophize This, which i don't think has a totalitarian or technocratic bent. it may be a little light on antistatism. the Hayek and Nozick episodes come to mind, and i think the only anarchist that got an episode is Throeau?
also sometimes technocrats are driven by good ideas, it's just that the for them 'normal' ways to put ideas into practice are terrible…